Equation 2 in the following paper derives the math for estimating orphan rate if you know the propagation delay of winning block headers travelling across the mining network. The propagation delay has a hashrate-weighted probability distribution that complicates the calculation. It also depends on the block time.
https://sites.cs.ucsb.edu/~rich/class/cs293b-cloud/papers/bitcoin-delay
An approximation, you can just use average propagation delay and the exponential CDF equation which is the probability of finding a block in "x" seconds:
CDF = 1 - e^(-x/T)
x = average propagation delay
T = block time = 600
This is the probability of an orphan occurring per block found.
The reasoning is like this: at any moment a winning header is found and propagating, this equation is the probability that someone else will find a block before that block has been seen by slightly less than half of the hashrate-weighted mining network. It gives a slight over-estimate of the orphan rate compared to the above paper. Using the median instead is an under-estimate. For a given orphan rate, you can use this equation backwards to estimate x.
The average propagation delay in BTC these days appears to be about x = 250 ms, so that CDF = 0.000416. The inverse of this 2,400, i.e. 1 orphan per 2,400 blocks which is the data I saw a couple of years ago. Assuming the same propagation delay x = 0.25 and T=150 for Litecoin, this gives 1 orphan per 600 blocks. I don't know the actual rate.
Since e^(-y) = 1-y when y is small, the equation simplifies to:
orphan_probability = x/T.
If you know the propagation delay and the orphan rate is higher than expected, it's evidence a big mining pool is doing a mild selfish mining attack. E.g., holding their winning blocks for 1 or 2 seconds in hopes of finding another, giving it better long-term success.